In general, no problem. Have to be careful which device it looks to for booting, though. I'm too lazy to look up the specs, but I'd say try it, pretty sure it will work, and no harm done if it doesn't ...
Yes, you can buy PCI IDE controllers. There's a company called Promise that makes some good ones. Maxtor also has one, though I think theirs is a Promise controller with Maxtor written on it ...
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